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斯文氧化反应的第一步是低温下，二甲基亚砜（1a)共振形成(1b)并与草酰氯（2）的亲核加成，生成第一个中间体（3）。此中间体迅速的分解为CO 2和CO，并生成氯化二甲基氯代锍盐（4）。 使用草酰氯作为脱水试剂时为了减少副反应，反应温度必须得低于-60 ...

Development of 18F-Labeled hydrophilic trans-cyclooctene as a bioorthogonal tool for PET probe construction.

构型稳定的 S-立体锍叶立德的分离与催化对映选择性合成，一直以来都是不对称合成领域中的重要挑战。锍叶立德作为反应性中间体，能够有效地参与多种合成转化，然而，其在硫立体中心固有的快速反转趋势使得这些反应性中间体在实际应用中的稳定性备受 ...

The University of Waterloo acknowledges that much of our work takes place on the traditional territory of the Neutral, Anishinaabeg, and Haudenosaunee peoples. Our main campus is situated on the ...

Multiple Triplet Metal-Centered Jahn-Teller Isomers Determine Temperature-Dependent Luminescence Lifetimes in [Ru(bpy)3 ]2.